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All
molecules can interact with other molecules, having the ability
to either attract or repel one another. There are several
important forces that govern the interactions of molecules;
it is the nature of these forces that directly determines
the melting points, boiling points, and solubility properties
of a particular compound. The most important forces found
in organic molecules are London dispersion forces, dipole-dipole
interactions, and hydrogen bonding.
London
Dispersion Forces
London
forces, one of the van der Waals forces, are the interactions
between temporary dipoles, a momentary separation of charge.
Electrons are in constant motion, and, at any given moment,
the movement of a single electron can disrupt the symmetrical
electron distribution on a molecule, creating a temporary
dipole that lasts for a fraction of a second.
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| London
forces: The random movement of electrons
causes a temporary dipole moment |
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These
partial charges on the molecule can then interact with partial
charges on other molecules. These forces are very weak; however,
the sum of many of these small forces can lead to a very significant
net force.
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