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Fused
ring systems that share more than two atoms are called bicyclic
molecules.
To name
bicyclic alkanes, you follow these three steps:
- Count
the total number of carbons in the entire molecule. This
is the parent name (eg. ten carbons in the system would
be decane)
- Count
the number of carbons between the bridgeheads, then place
in brackets in descending order. (eg. [2,2,1])
- Place
the word bicyclo at the beginning of the name.
Example:
Name the following molecule by the IUPAC system of nomenclature.

- Count
the total number of carbons. In this case there are 7 carbons
so the parent name is heptane
- Count
the total number of carbons between bridgeheads. In this
case there are 2, 2, and 1 carbons between the bridgehead.
Placed in descending order between brackets it is [2,2,1]
- Put
the word bicyclo in the front of the name
The name
is thus bicyclo [2,2,1] heptane
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Now you try naming these (click on the molecule to get
the answer)
  
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